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Apotheon
§ SUPPLEMENT·Evidence: strong

Vitamin B3

Vitamin B3 is a family of four clinically distinct compounds that share one destination (NAD+/NADP+) but diverge in pharmacology, safety, and indication: - Niacin (nicotinic acid) — GPR109A agonist; causes cutaneous flushing; historically used for dyslipidemia but definitively ab

Clinical Summary

Vitamin B3 is a family of four clinically distinct compounds that share one destination (NAD+/NADP+) but diverge in pharmacology, safety, and indication:

  • Niacin (nicotinic acid) — GPR109A agonist; causes cutaneous flushing; historically used for dyslipidemia but definitively abandoned after HPS2-THRIVE (2014) and Cochrane 2017 showed no cardiovascular benefit. The 2024 Hazen/Ferrell Nature Medicine paper identified niacin's terminal metabolite 4PY as causally driving endothelial VCAM-1 and atherosclerosis risk — a mechanistic explanation for the null/harm observed in cardiovascular trials.
  • Nicotinamide (niacinamide) — Amide form; no GPR109A activation, no flushing, no glucose dysregulation; well-tolerated to 3 g/day. The strongest evidence-to-practice match in the entire B3 family is the ONTRAC trial (500 mg BID prevents recurrent non-melanoma skin cancer in immunocompetent high-risk adults).
  • Nicotinamide Riboside (NR) — Reliably raises blood NAD+ (5/5 surrogate endpoint) but nine years of RCTs have failed to translate this into clinical outcomes for metabolic, cognitive, or sarcopenia endpoints. Narrow 2024-2025 positive signals in COPD, PAD, Werner syndrome, and plasma pTau-217 keep the hypothesis alive.
  • Nicotinamide Mononucleotide (NMN) — Smaller Western trial base; Japanese consumer market-dominant; FDA reinstated supplement status after 3-year exclusion. Raises NAD+ comparably to NR but three 2024-2025 meta-analyses show no effect on glucose, lipids, or muscle function. Christen 2026 Nat Metab revealed both NR and NMN rely on gut microbial conversion to nicotinic acid for NAD+ elevation — collapsing mechanistic product differentiation.

Who benefits most: (1) patients with deficiency (pellagra, alcoholism, isoniazid therapy, celiac, extensive small-bowel resection) — definitive repletion; (2) immunocompetent adults with history of ≥2 non-melanoma skin cancers — nicotinamide 500 mg BID; (3) patients considering niacin for lipids — don't. Everyone else is in WATCH territory: the longevity promise remains mouse-dominant, human surrogate-biased, and commercially hyped. "Pellagra is rare in wealthy nations" is the correct starting prior; everything beyond deficiency repletion is probabilistic.

Indications & Evidence

IndicationEvidenceTypeBHSafetyEffect SizePopulationDoseDurationKey PMID
Pellagra treatment5/5DC9--100% response (historical)All deficientNicotinamide 100 mg TID3-4 wk14693013
Isoniazid-induced pellagra (prevention)5/5DC9--Prevents with B6+nicotinamideINH-treated malnourishedNicotinamide 50-100 mg + B6 25-50 mgDuration of INH3451228, 35427527
Non-melanoma skin cancer recurrence (immunocompetent)4/5PC7--NMSC -23% (ONTRAC)≥2 prior NMSC, healthyNicotinamide 500 mg BID12 mo26488693
NMSC in solid-organ transplant recipients2/5RC3--Null (ONTRANS failed)Kidney transplant recipientsNicotinamide 500 mg BID12 mo36856616
Blood NAD+ elevation (NR)5/5SE8--+40-150% dose-dependentHealthy adultsNR 100-2000 mg/day2-12 wk29599478, 29184669
Blood NAD+ elevation (NMN)4/5SE8--+11-38%Healthy adultsNMN 250-1250 mg/day4-12 wk33888596, 36482258
Insulin sensitivity (NMN, prediabetic postmenopausal women)2/5UCC3--Muscle-only improvement (N=25)Prediabetic postmenopausal FNMN 250 mg/day10 wk33888596
Glucose/lipid improvement (NMN, general)1/5RC2--Null — 3 meta-analysesMixed adultsNMN 250-1200 mg/day4-16 wk39531138, 39116016, 39111741
Muscle function / sarcopenia (NR+NMN ≥60 yo)1/5RC2--Null meta (no SMI/HGS/gait benefit)Adults ≥60Mixed NR/NMN dosesVariable40275690
Cognitive function (NR in MCI)1/5RC2--Null cognition; pTau-217 ↓ (biomarker)MCI/SCDNR 250-1000 mg/day8-12 wk36859743, 39817194
COPD airway inflammation3/5PC4--IL-8 -52.6%, lasting 12 wk postCOPD ex-smokersNR 2 g/day6 wk39548320
Peripheral artery disease (6-min walk)3/5PC3--+17.6 m vs placeboPADNR 1 g/day6 mo38871717
Hypertension (NR, ambulatory BP)1/5RC2--Null (NR+Ex vs PBO+Ex)Adults ≥55NR 1 g/day + walking6 wk40770531
Werner syndrome (arterial stiffness, skin ulcer)3/5UCC3--CAVI ↓, ulcer area ↓Werner syndromeNR 1 g/day26 wk crossover40459998
Long-COVID cognition/fatigue1/5RC2--Null primary (24 wk, 2 g NR)Long-COVIDNR 2 g/day24 wk41357333
Glaucoma neuroprotection3/5PC4--Visual-field improvement (Ph2); Ph3 pendingOAG on IOP therapyNicotinamide 1.5-3 g/day ± pyruvate6-24 mo34792559, 32721104
IBD (GPR109A anti-inflammatory)3/5ME3MONPreclinical + observationalUC/Crohn'sNiacin 500-1000 mg divided8-12 wk24412617
Parkinson's disease (NR, NADPARK)2/5UCC3--Cerebral NAD ↑, MDS-UPDRS nsEarly PDNR 1 g/day30 dNCT03568968
Cardiovascular outcome reduction (niacin)5/5 nullRC9WARNNo MACE benefit + harm (4PY signal)CVD risk/2° preventionNiacin 1-2 g/dayLong-term28616955, 22085343, 25014686, 38374343
Longevity / lifespan extension (human)1/5ME1--No human outcome dataAnyAny B3 formLifelong
Topical skin (pigmentation, acne, barrier)4/5PC6--Comparable to 4% hydroquinone / 1% clindamycinAdults with NMSC/hyperpigmentation/acneTopical niacinamide 2-10%8-12 wk40005371

Reading this table: Stars = evidence volume for THIS specific claim. Type = causal-relationship classification. BH = Bradford Hill /9. Safety = FAERS/trial signals specific to this indication pathway. One row = one decision.

Hard rule: Star rating never exceeds the causal-taxonomy ceiling (e.g., ME caps at 2/5; SE caps at 5/5 for replicated surrogate but cannot be upgraded to clinical outcome).

Type codes: DC=Direct causation | PC=Probable causal | UCC=Unreplicated causal | BC=Biomarker correlation | SE=Surrogate endpoint | ME=Mechanistic extrapolation | AHE=Animal→human | OA=Observational | RC=Refuted claim | CF=Confounded | FA=Folk/anecdotal | NE=No evidence BH: 7-9 strong | 5-6 moderate | 3-4 weak | 1-2 speculative | 0 none Safety flags: -- None | MON Monitor | WARN Signal documented — see Safety | AVOID Contraindicated

Prescribing

Dosing Table

PopulationDoseTimingNotes
Adults 19+ (RDA)16 mg NE M / 14 mg NE FAny1 mg niacin = 60 mg tryptophan
Pregnancy18 mg NEAnyStay ≤35 mg UL; avoid NR/NMN (no data)
Lactation17 mg NEAnyPrenatal vitamin covers
Pellagra (acute)Nicotinamide 100 mg TIDWith meals3-4 wk; GI improves 24-48h, skin 3-7d
Subclinical deficiencyNicotinamide 50-100 mg/dayMorning2-4 wk then RDA
NMSC secondary prevention (immunocompetent)Nicotinamide 500 mg BIDMorning + eveningContinuous; ONTRAC protocol
Isoniazid prophylaxis (malnourished)Nicotinamide 50-100 mg + B6 25-50 mgWith INHDuration of INH therapy
NAD+ repletion (healthy aging)NR 300-1000 mg/dayMorning2-4 wk to steady state
NAD+ repletion (nicotinamide alternative)Nicotinamide 250-500 mg/dayMorningCost-effective; weaker NAD+ rise than NR
Glaucoma neuroprotection (emerging)Nicotinamide 1.5-3 g/day ± pyruvate 1.5 g/dayDivided BIDPhase-3 NAMinG pending 2027
Dyslipidemia (historical)DO NOT USECochrane 2017 null + 2024 4PY harm mechanism

Formulation Table

FormBioavailabilityWhen to UseCost (USD/mo)
Nicotinamide (niacinamide)Near-completeDefault for most indications; pellagra, NMSC, NAD+ support$3-8
Niacin IR (nicotinic acid)100%Niche: severe hypertriglyceridemia unresponsive to fibrates + statin; IBD GPR109A trial$5-12
Niacin ER (Niaspan Rx)100%, delayedAvoid — marginal flushing benefit, lingering hepatotoxicity risk$25-80
Niacin SR (OTC slow-release)100%, extendedAvoid — highest hepatotoxicity; OTC "wax matrix" products$10-18
Inositol hexanicotinate ("no-flush niacin")Poor (~20-40%)Avoid — does not meaningfully release niacin (Meyers 2003)$12-20
Nicotinamide Riboside (Niagen)40-60% dose-dependentNAD+ repletion where premium budget tolerable$35-60
Nicotinamide Mononucleotide (NMN)10-40%Per preference; not superior to NR for NAD+ elevation$40-80
Topical niacinamide (2-10%)N/A (local)Hyperpigmentation, acne, barrier, post-procedure$10-40

Condition-Specific Protocols

Non-Melanoma Skin Cancer Recurrence (Immunocompetent)

Evidence: 4/5 | Key PMID: 26488693 (ONTRAC) + 40498148 (Hwang 2025 SOTR cohort) + 35134311 (Mainville meta)

Phase 1: Initiation (Weeks 1-2)

  • Nicotinamide 500 mg once daily to establish tolerance
  • Confirm no history of sustained-release niacin or daily high-dose (>3 g) use
  • Discuss with dermatologist — this is adjunct to surveillance, not replacement

Phase 2: Therapeutic (Months 1-12)

  • Nicotinamide 500 mg BID (morning + evening) with meals
  • Continue standard dermatology follow-up every 6 months
  • Expected: ~23% reduction in new NMSC (BCC or SCC) vs placebo
  • AE profile matches placebo in ONTRAC — minimal monitoring

Phase 3: Maintenance (Month 12+)

  • Continue 500 mg BID indefinitely if well-tolerated — benefit disappears after cessation per ONTRAC post-hoc
  • Reassess annually; consider discontinuation if no new NMSC for 3+ years and low-risk skin phenotype

Drug Interaction Timing: No clinically meaningful spacing required at 1 g/day. If on carbamazepine/phenytoin, no documented interaction but monitor. Expected Outcomes: ~1 fewer NMSC per ~5 high-risk patients per year; no effect on melanoma Stop/Reassess Criteria: LFT elevation >2× ULN (unexpected at this dose); new finding of solid-organ transplant (benefit does not extend — ONTRANS 2023 null); pregnancy

IMPORTANT CAVEAT: Allen 2023 NEJM (PMID 36856616) found nicotinamide 500 mg BID did NOT reduce NMSC in kidney transplant recipients. The 2026 Tan/Williams reappraisal (PMID 41505062) flags population dependence. This protocol applies to IMMUNOCOMPETENT adults only.

Pellagra / Niacin Deficiency

Evidence: 5/5 | Key PMID: 14693013 (Hegyi review)

Acute pellagra (4Ds: dermatitis, diarrhea, dementia):

  • Nicotinamide 100 mg TID × 3-4 weeks (oral; IM/IV if severe malabsorption)
  • Add B-complex (often coexisting deficiencies)
  • Response: diarrhea 24-48h → dermatitis 3-7d → cognition 7-14d (may be incomplete if chronic)
  • Address underlying cause: alcoholism (FAERS + literature confirm), INH therapy, anorexia, malabsorption

Maintenance after acute: Nicotinamide 100 mg/day + dietary counseling (poultry, fish, legumes, enriched grains)

Isoniazid prophylaxis: Vitamin B6 25-50 mg/day (standard with INH); add nicotinamide 50-100 mg/day if malnutrition/alcoholism/low dietary niacin. Malawi 2017 pellagra outbreak during IPT scale-up established the need (PMID 35427527).

Safety

Interactions Table

InteractantEffectManagement
StatinsAdditive hepatotoxicity + myopathy (niacin specific)Avoid niacin-statin combination; nicotinamide/NR/NMN compatible
Diabetes medicationsNiacin worsens glycemic control via GPR109A (+0.3-0.5% HbA1c)Avoid niacin in diabetes; nicotinamide/NR/NMN safe (NMN may modestly improve in prediabetic F)
IsoniazidInduces niacin deficiency (blocks B6-dependent Trp → niacin)B6 25-50 mg + nicotinamide 50-100 mg daily during INH
Alcohol (chronic)Depletes NAD+, impairs absorption, additive hepatotoxicity with niacinUse nicotinamide 100-300 mg/day in chronic alcoholism; avoid niacin
WarfarinPossible INR enhancement (niacin; inconsistent)Monitor INR weekly ×4 weeks when initiating niacin
AnticonvulsantsMinimal; theoretical enzyme inductionStandard monitoring
Carbidopa/LevodopaNone documentedStandard
NR/NMN + exercisePossible blunted training adaptation (rat data, PMID 32917636); negative human HTN+Ex trial (PMID 40770531)Athletes: avoid high-dose NR/NMN during training cycles

Contraindications

  • Severe renal impairment (GFR <30) — metabolite accumulation risk, all forms
  • Active liver disease / transaminases >3× ULN — all forms; niacin highest risk
  • Active peptic ulcer disease — niacin only (stimulates gastric acid)
  • Uncontrolled gout — niacin only (raises uric acid ~5-10%)
  • Pregnancy/lactation + NR/NMN — no safety data; stay at RDA from prenatal vitamins
  • Diabetes (any type) + niacin — use nicotinamide/NR/NMN instead
  • Prior 4PY-signal cardiovascular risk (theoretical) — avoid high-dose niacin >500 mg/day in atherosclerotic disease

Adverse Effects (ranked by frequency)

Niacin (nicotinic acid) — genuine drug signal:

  • Flushing (70-90% at ≥50 mg IR; 15-30 min onset; 30-60 min duration; tachyphylaxis in 1-2 wk)
  • GI nausea/dyspepsia (5-12%)
  • Hyperglycemia / HbA1c rise (10-20% at >1 g/day)
  • Hyperuricemia / gout flare (5-10%)
  • Hepatotoxicity (<1% IR; 3-10% SR at >1 g/day; 43 FAERS hepatic failure reports)
  • Atrial fibrillation (small excess in HPS2-THRIVE / AIM-HIGH)
  • Rare: macular edema, myopathy (with statins), fulminant hepatic failure (SR formulations)

Nicotinamide — supplement-noise pattern, no hepatotox/flushing signal up to ~3 g/day:

  • GI nausea (5-10% at >1 g)
  • Headache (uncommon)
  • Rare reported LFT elevation at chronic >3 g/day (orthomolecular megadose territory)

NR — 32 total FAERS reports, no signal:

  • Occasional nausea / GI (empty-stomach dosing)
  • Sleep disruption if dosed late PM
  • Headache rare
  • No hepatotoxicity signal across 40+ completed trials to 2 g/day

NMN — 4 FAERS reports (all concomitant-role); no independent signal:

  • Insomnia if dosed late (community-consistent)
  • Mild GI (minority)
  • Rare platelet/bruising case reports (low-N, unverified causality)

FAERS Signal Table (BioMCP, 2026-04-17)

ReactionFAERS ReportsSuspect Drug?SeriousnessLinked IndicationNotes
Niacin — drug ineffective966Yes (99.9% suspect)LowCVD/lipidExpected: Rx withdrawal from guidelines
Niacin — flushing393YesMildAll niacin usesExpected pharmacology (GPR109A)
Niacin — hepatic failure43YesSeriousAll niacin usesConcentrates in SR/ER formulations
Niacin — death-outcome reports245YesFatalElderly polypharmacyCo-terms: falls, pneumonia, renal/cardiac failure — confounded
Nicotinamide — all reactions5,953VariableLow-moderateMixedNo flushing, no hepatotox, no death signal — supplement-noise pattern
NR — all reactions32Mostly concomitantLowSample too small for signal detection
NMN — all reactions4All concomitantNo independent signal

Reading FAERS data: Niacin's 13,483 reports with 99.9% suspect-drug assignment reflect its status as a prescription drug for decades — this is a genuine AE profile. Nicotinamide's 5,953 reports show the diffuse off-label-use/fatigue/nausea pattern typical of elderly polypharmacy confounding, not compound harm. NR and NMN FAERS absence reflects regulatory category (supplement not in FDA drug database), not safety endorsement.

Monitoring Table

TestWhenTarget
LFTs (AST/ALT/AP/bili)Baseline + 6 wk + 12 wk for niacin >500 mg/day or nicotinamide >2 g/day<3× ULN
Fasting glucose + HbA1cBaseline + every 3 mo if on niacinNo HbA1c rise >0.3%
Uric acidBaseline if gout historyNo rise >1 mg/dL
Creatinine / eGFRBaseline; annually if >60 yo or high-doseStable
CK (if on statins + niacin)Baseline + if muscle symptoms<10× ULN
Urinary N-methylnicotinamideIf suspected pellagra / subclinical deficiency>0.8 mg/g creatinine

Special Populations

Renal Impairment

GFR RangeDose AdjustmentRationaleEvidence
60-89 (mild)StandardNormal clearanceModerate
30-59 (moderate)Reduce all forms by 50%Metabolite accumulation (2PY, 4PY, N-methylnicotinamide)Low
<30 (severe)Avoid niacin; nicotinamide 100-250 mg only under supervision4PY accumulation particularly concerning post-Hazen 2024Low-moderate

Hepatic Impairment

SeverityDose AdjustmentRationaleEvidence
Child-Pugh A (mild)Avoid niacin; nicotinamide/NR/NMN standard doseNiacin-specific hepatotoxicityModerate
Child-Pugh B (moderate)Avoid all forms >RDA until baseline LFTs stableReduced conjugation/methylation capacityLow
Child-Pugh C (severe)RDA from diet onlyDecompensated liver cannot clearLow

Pregnancy & Lactation

  • RDA 18/17 mg NE — covered by prenatal vitamin
  • Nicotinamide: Category C (inconclusive); stay ≤35 mg UL from supplements
  • NR, NMN: No safety data — avoid
  • Niacin >35 mg/day during pregnancy: rare indication (severe hypertriglyceridemic pancreatitis); specialist only

Synergies & Stacking

Co-nutrientWhyEvidence
Vitamin B6Required cofactor for kynurenine pathway (Trp → niacin)5/5 biochemistry
Vitamin B2Kynurenine 3-monooxygenase cofactor4/5 biochemistry
Vitamin B12 + FolateSupport SAM regeneration for NNMT-mediated niacin methylation3/5 at mega-dose niacin
TryptophanDirect precursor (60:1 conversion); adequate protein reduces niacin need5/5 biochemistry
PyruvateAdditive in glaucoma neuroprotection RCTs3/5 Ph2 (PMID 34792559)
Aspirin 325 mgBlocks niacin flushing (COX → PGD2) when taken 30 min pre-dose3/5 mechanism
TrigonellineNovel NAD+ precursor (coffee); Membrez 2024 Nat Metab2/5 emerging
NAD Plus (IV)Shared endpoint; no NAD+ IV outcome trials exist (Gallagher 2026 PRISMA)2/5 surrogate only

Antagonisms: alcohol (NAD consumption + hepatotoxicity), isoniazid (pellagra induction), high-dose SAM-e + mega-dose nicotinamide (methyl depletion theoretical).

Individual Response Modifiers

Sex-Specific Considerations

FactorMaleFemaleClinical Implication
Tryptophan → niacin conversionStandardShifted toward serotonin during pregnancy / on oral contraceptivesPregnant women/women on OCPs may have reduced endogenous niacin synthesis — prioritize dietary adequacy
NMN insulin-sensitivity benefitNo effect (Yoshino pilot null in men)Benefit in prediabetic postmenopausal women (Yoshino 2021)Sex-restricted single-trial signal — do not extrapolate to males
Niacin flushing intensityStandardPossibly more intense (estrogen-modulated PGD2)Women may need slower titration; no formal RCT
HepatotoxicityStandardPossibly higher baseline susceptibilityMonitor LFTs more frequently in women on niacin >1 g/day
Pregnancy/lactation + NR/NMNN/ANo data; avoidUse RDA from prenatal vitamin only
Study population biasMost NR trials mixedYoshino NMN study women-only; most glaucoma trials mixedFlag sex-restricted findings in evidence interpretation

Genetic Modifiers

Gene (SNP)VariantEffect on This CompoundEvidenceAction
Niacin-4PY pathway (rs10496731)Higher 2PY/4PY levels → higher sVCAM-1 → MACE riskGWAS (106k meta) + mendelian randomization, Ferrell 2024 PMID 38374343Hypothetical: carriers may have excess atherogenic risk from niacin — not clinically actionable yet but strengthens case against high-dose niacin
MTHFR (rs1801133)C677TIncreased SAM demand for N-methylation at high-dose nicotinamide → may deplete methyl poolReplicated biochemistryTT homozygous + mega-dose nicotinamide (>2 g/day): ensure methylfolate + B12
NNMT (various)MultipleOverexpression reduces NAD+ salvage; associated with neurodegeneration (Akl 2025 review PMID 40221009)Preclinical; emergingNo human-actionable guidance yet — research only
Slc12a8Proposed NMN intestinal transporter (mouse); human relevance disputed (Christen 2026 reframes NR/NMN as gut-microbiota mediated)Mouse + disputed humanDo not use Slc12a8 status as a reason to prefer NMN over NR
NAMPT variantsLow-activityReduced endogenous NAD+ salvage; carriers may benefit more from precursor supplementationResearch stageNot clinically actionable

No compound-relevant evidence for ABO/VWF, FUT2, APOE, VDR, COMT, BCMO1, CYP2D6/3A4, SOD2, SLC23A — these variants do not meaningfully alter Vitamin B3 response.

Community & Anecdotal Evidence

Disclaimer: Online community reports. Not clinical evidence. N-sizes approximate. Selection bias, placebo effect, and recall bias inherent.

Dominant Sentiment (by form)

  • Niacin: Polarized. 50/50 "life-changed for my Lp(a)" vs "quit within a week from flush." Older, cardiology-adjacent, orthomolecular-overlapping. Low thousands of observable English voices.
  • Nicotinamide: Strongly positive. Skincare dominates (tens of thousands); oral anti-anxiety / sleep secondary. The Ordinary 10% + Zinc 1% has tens of thousands of reviews.
  • NR (Tru Niagen): Mixed-positive. Commercially dominant US. Low thousands of engaged longevity users. Older skew. "Safer bet than NMN."
  • NMN: High enthusiasm / hype-cycle energy. Japanese consumer market massive (hundreds of thousands). English communities mid-thousands. Sinclair-driven.

What Users Report

Reported EffectFrequencyTypical OnsetSource Communities
Lipid changes (niacin)Common — HDL↑, TG↓, Lp(a)↓4-12 wkPeter Attia listeners, cholesterol-focused subreddits
Flush discomfort → tolerance (niacin)Common1-14 dAll niacin users
Skin hyperpigmentation / acne improvement (topical niacinamide)Common8-12 wkr/SkincareAddiction, r/AsianBeauty
Anti-anxiety (oral nicotinamide 500 mg – 1.5 g)Moderate NSame-day – 1 wkRay Peat / bioenergetic, nootropics
Sleep improvement (oral nicotinamide)Majority positive; paradoxical minoritySame-nightLowToxinForum, Phoenix Rising
Energy (NMN > NR)Moderate2-6 wkr/longevity, r/Biohackers
Cognitive clarity (NMN, 40+)Common in 40+; rare in 30s4-8 wkLongecity, Sinclair ecosystem
Libido (NMN, 50+ men)Moderate reports4-8 wkBiohacker forums
Gray-hair "reversal" (NMN)Small-N anecdoteMonthsr/longevity — skeptical consensus
Insomnia if dosed late (NR/NMN)CommonSame-nightAll NAD+ communities
Joint mobility (NR long-term)Small-N3-6 moLongecity long-term threads

Community Dosing vs Clinical

SourceDoseRouteNotes
Clinical pellagra300 mg nicotinamideOral TID5/5
Clinical NMSC500 mg BID nicotinamideOral4/5 ONTRAC
Clinical NR300-1000 mgOral AM4/5
Community niacin (lipids)500-2000 mg IRTitratedAggressive
Community megadose nicotinamide (orthomolecular)3-17 gOral divided️ hepatotox territory
Community NMN (biohacker)600-1000 mgOral AMSinclair's 1 g reference
Community NMN (Japan consumer)125-300 mgOral AMLower than Western
"Drug test detox" myth (niacin)3-5 g single doseOral️ ER visits documented

Popular Stacks (Community)

Stack CombinationReported PurposeEvidence Level
NR/NMN + TMG (trimethylglycine)Offset methylation demand2/5 theoretical
NR + Pterostilbene (Elysium Basis)"Sirtuin synergy"2/5 preclinical
NMN + Resveratrol (Sinclair protocol)Longevity2/5 extrapolated from mice
Topical niacinamide + retinol + vitamin CSkincare trifecta3/5 dermatology consensus (old "don't mix with C" myth debunked)
Niacin IR + aspirin 325 mg 30 min preFlush suppression3/5 mechanism-validated
Nicotinamide 1 g + magnesium + glycine"Sleep stack"2/5 community

Red Flags & Skepticism Notes

  • MLM: Modere (Utah; shut down Apr 2024, acquired by Shaklee) sold adjacent anti-aging products but not NMN-focused. True MLM penetration of NR/NMN is minor — DTC/specialty retail dominates.
  • Influencer concentration: David Sinclair (MetroBiotech co-founder — direct NMN drug-development conflict; disclosed but pervasive across media appearances), Charles Brenner (ChromaDex CSO — NR advocate with direct commercial interest), Rhonda Patrick (Tru Niagen affiliated), Dave Asprey (paid promotions), Ben Greenfield (affiliate structures). Peter Attia is notably skeptical of NR/NMN for healthy adults and does not take them.
  • Astroturfing signals: Charava "What Reddit users say about NMN" = UK retailer commercial content masquerading as synthesis. Retailer SEO farms: omre.co, nmn.com, hello100.com, wonderfeel — all retailer-owned. "Clinically proven to raise NAD+ by X%" on virtually every NMN/NR label refers to surrogate PK endpoints, not clinical outcomes.
  • Commercial bias: ChromaDex funds much of the NR trial base; Elysium funds separate subset (Norheim 2024 COPD); Sinclair's MetroBiotech funds key NMN trials (NCT05878119). Pencina 2023 JCEM (MIB-626) explicitly showed NAD+ rose but physical function did not — sponsor did not stop promoting.
  • Quality scams: 2022-2024 Amazon NMN era saw many products assaying <10% of label. ChromaDex 2024 claims 87% of NR products miss label (conflicted source; same concern for NMN). Renue, Thorne, ProHealth, DoNotAge, Jinfiniti, NOVOS maintain COA transparency.

Folk vs Clinical Reality Check

Community experience ALIGNS with clinical data for: niacin lipid effects and flush tolerance development; topical niacinamide efficacy for skin; oral nicotinamide anxiolytic at ~1 g; sleep disruption from late-evening NR/NMN; NR at ~300 mg being broadly safe. Community experience DIVERGES from clinical data on: longevity/lifespan claims for NR/NMN (mouse data extrapolated, human outcome data absent), orthomolecular schizophrenia megadose (APA 1973 null + chronic hepatotox risk), "no-flush niacin" (IHN) being equivalent to niacin (Meyers 2003: it is not), NMN "reverses gray hair" (no objective data), and drug-test detox folklore (false + harmful). The most likely explanations for divergence are placebo (subjective energy/clarity highly susceptible), dosing disparities (community often 2-3× clinical), population differences (50+ self-selects into responder cohort), and stacking confounders (nearly no user takes just one B3 form).

Deep Dive: Mechanisms & Research

The four B3 forms converge on NAD+/NADP+, cofactors for >400 enzymes (glycolysis, TCA cycle, oxidative phosphorylation, PARP DNA repair, sirtuin deacetylation, CD38 consumption). NAD+ declines ~50-70% between ages 40-80 via increased CD38 and NADH oxidation. Three NAD+ biosynthesis routes exist: de novo (tryptophan → kynurenine, B6-dependent), salvage (nicotinamide → NMN → NAD+ via NAMPT, the rate-limiting step), and Preiss-Handler (nicotinic acid → NAMN → NAD+).

2026 paradigm shift (Christen Nat Metab, PMID 41540253): The first rigorous human head-to-head (n=65, 14 days) showed NR and NMN raise NAD+ comparably, but ex vivo microbiota analysis revealed both are converted to nicotinic acid by gut bacteria — the actual effective NAD+ booster working via Preiss-Handler. Nicotinamide does NOT reach this conversion pathway as efficiently. This collapses the "NMN is closer to NAD+" and "NR bypasses NAMPT" marketing claims: in humans, gut microbiota dominate precursor selection, and individual variation in microbial composition predicts response. Supplement differentiation is largely manufactured.

2024 Hazen/Ferrell paradigm update (Nat Med, PMID 38374343): Niacin's terminal methylation metabolite 4PY (N1-methyl-4-pyridone-3-carboxamide) is causal for endothelial VCAM-1 induction in mice and predicts 3-year MACE in three independent cohorts (adjusted HR 1.89-1.99). The rs10496731 variant is linked to both 2PY/4PY levels and sVCAM-1 in 106,000-subject GWAS meta-analysis. This retrospectively explains HPS2-THRIVE and AIM-HIGH: niacin's lipid benefit is real but its terminal metabolite independently drives atherosclerosis. Any remaining high-dose niacin use for lipids carries this mechanism as a ceiling on benefit.

GPR109A (HCA2) receptor — activated by niacin (not nicotinamide) on adipocytes, Langerhans cells, and colonic macrophages. Drives flushing (phospholipase A2 → PGD2 → DP1/EP2/EP4 vasodilation; TRPV1 also contributes — PMID 39322100). Same receptor drives anti-inflammatory effects in IBD (Singh 2014 Immunity), but butyrate is the endogenous ligand, not dietary niacin.

Sirtuins (SIRT1-7) — NAD+-dependent deacetylases. SIRT1 regulates PGC-1α (mitochondrial biogenesis), FOXO (stress resistance), CLOCK/BMAL1 (circadian). Sinclair's hypothesis: NAD+ decline reduces sirtuin activity → supplementation restores it. Human evidence: NAD+ rises consistently; sirtuin activity in tissues harder to measure; clinical outcomes largely null.

PARPs — DNA-damage-responsive NAD+ consumers. Overactivation depletes cellular NAD+. Theoretical longevity target; human outcome data absent.

SARM1 — emerging axon-degeneration checkpoint; NAD+ depletion activates. Translational research PMID 41502156, 40097763. Nicotinamide riboside small-fiber neuropathy trials terminated (NCT03642990, NCT03685253) — mechanism plausible, clinical translation fragile.

Clinical Trials (BioMCP / ClinicalTrials.gov snapshot 2026-04-17)

NCT IDTitle/FocusPhaseStatusConditionsNKey Dates
NCT00461630HPS2-THRIVE (niacin + laropiprant + statin)Ph3CompletedCVD secondary prevention25,6732014 — null MACE, excess AEs
NCT00120289AIM-HIGH (niacin + statin)Ph3CompletedLow HDL CVD3,4142011 — stopped for futility
NCT02491567ONTRAC (nicotinamide NMSC)Ph3CompletedNMSC prevention3862015 — positive (NEJM)
NCT02355756ONTRANS (nicotinamide NMSC in transplant)Ph3CompletedKidney transplant + NMSC1582023 — failed (NEJM)
NCT05405868NAMinG (nicotinamide glaucoma)Ph3RecruitingOAG neuroprotection496Completion 2027
NCT05740722NR progressive MSPh2RecruitingProgressive MS300Completion 2027
NCT03568968NADPARK (NR in Parkinson's)Ph3CompletedEarly PD400Neutral on MDS-UPDRS
NCT05878119MIB-626 (NMN drug, Sinclair/Metro Biotech)Ph2Completed Aug 2025Healthy 19-40 yo124Results pending — will reshape NMN evidence
NCT04990869NR COPD (Norheim)Ph2CompletedCOPD airway inflammation402024 positive (Nat Aging)
NCT06208527NADage (NR frailty)Ph2RecruitingFrailty ≥75 yoPivotal if positive
NCT05732051NR breast cancer cardioprotectionPh2RecruitingBrCa on anthracyclines
NCT04844528Nicotinamide in CLL + NMSCPh2RecruitingCLL patients
NCT06971224NADream (NR sleep)Ph2RecruitingSleep quality
NCT06991712NMN vs NR glaucoma head-to-headPh2RecruitingOAG

Regulatory Status (2026)

  • Niacin: Prescription drug (Niacor, Niaspan, multiple ANDAs). Removed from CVD guidelines post-HPS2-THRIVE; restricted to severe hypertriglyceridemia adjunct (AACE 2025 PMID 39919851, ACC/AHA 2018). Most ER formulations discontinued.
  • Nicotinamide: GRAS dietary supplement; no FDA/EMA drug approvals; safe to 3 g/day per consensus.
  • Nicotinamide Riboside: FDA NDI acknowledged 2018, GRAS 2018; EU Novel Food authorized 2020; Niagen is trademarked to Niagen Bioscience (formerly ChromaDex).
  • NMN: FDA excluded from supplement definition Nov 2022 (prior IND by MetroBiotech under FDCA 201(ff)(3)(B)) → reversed 29 Sept 2025 → NDI status formally reinstated 2 Dec 2025 via letters to major ingredient suppliers. NMN is once again a lawful US dietary supplement. Japan: legal food ingredient (large consumer market). China: supply-chain dominant. EU: novel food unauthorized. Australia/NZ: banned since 2022-2024.

Ataraxia Verdict (as of 2026-04-17)

Evidence Classification (Mode 5)

ClaimRelationshipBradford HillSafety FlagKey Weakness
Pellagra treatmentDC9--Historical evidence, no equipoise for modern RCT
NMSC prevention (immunocompetent)PC7--Single major RCT (ONTRAC); benefit requires continuous use
NMSC prevention (transplant)RC3--ONTRANS 2023 definitively negative
NAD+ elevation (NR/NMN)SE8--Surrogate only — does not predict clinical outcome
Insulin sensitivity NMN (prediabetic PM women)UCC3--Yoshino 2021 N=25 not replicated; 3 meta-analyses null
Muscle/sarcopenia NR+NMN ≥60RC2--Prokopidis 2025 definitive null
Cognition NR in MCIRC2--Orr 2023 null; pTau-217 biomarker insufficient
CVD prevention niacinRC9 (for null)WARNCochrane 2017 + Hazen 2024 4PY mechanism
COPD inflammation NRPC4--Single Ph2, industry-funded
PAD walking NRPC3--Single Ph2, modest effect, needs replication
Glaucoma neuroprotectionPC4--Ph2 positive; Ph3 NAMinG pending 2027
Longevity humanME1--Pure mouse extrapolation; no human outcome data
Topical skin (niacinamide)PC6--Consistent derm evidence; effect size moderate

Hype Check (Mode 1)

  • Appeal to nature: "vitamin = safe" conflates RDA repletion with pharmacological mega-dosing; false for niacin (4PY mechanism), theoretical for long-term high-dose nicotinamide
  • Species generalization: "NR/NMN extends lifespan in mice → will extend lifespan in humans" is the dominant unsupported inference across the longevity space
  • Cum hoc ergo propter hoc: "NAD+ declines with age AND aging is bad → restoring NAD+ will reverse aging" is correlation not causation (Gallagher 2026 PRISMA confirms insufficient evidence)
  • Authority cascade: Sinclair book + podcast appearances + affiliated companies create circular citation that substitutes repetition for replication
  • Surrogate-endpoint trap: Virtually every NR/NMN product claim rests on "raises NAD+ by X%" — a surrogate with poor clinical translation record (vitamin E precedent: raised antioxidant markers, did nothing for outcomes)
  • Historical cherry-pick: "Coronary Drug Project showed niacin reduced MI" ignores pre-statin era baseline and is overwhelmed by AIM-HIGH, HPS2-THRIVE, Cochrane 2017

Evidence Gaps

  • No human outcomes trials for NAD+ IV (Gallagher 2026 PRISMA)
  • No Phase-3 MACE-endpoint trial for any NAD+ precursor
  • No replication of Ferrell/Hazen 4PY causal mechanism in independent cohorts
  • No head-to-head niacin vs nicotinamide vs NR CV-safety RCT
  • No sex-stratified hepatotoxicity/flushing niacin trial
  • No pregnancy/lactation safety data for NR/NMN
  • No data on long-term (>5 yr) NR/NMN safety at biohacker doses
  • Zero recent RCTs on niacin for alopecia, bone density, or phosphate-binding in CKD (NOPHOS terminated)
  • NADSYN1, SLC22A6, NNMT pharmacogenomic outcome data essentially absent
  • Human replication of Slc12a8 NMN transporter remains disputed — Christen 2026 reframes the entire mechanism as gut-microbial

Bias Flags (Mode 4)

  • Sinclair commercial conflicts: MetroBiotech (MIB-626 NMN drug), Tally Health, Leap Years — directly affect interpretation of NMN evidence (and 2022 FDA NDI exclusion coincided with MetroBiotech's drug pathway)
  • ChromaDex funds a large fraction of NR trial base; Brenner is CSO and vocal NMN critic — interpret Brenner-authored statements comparing NR to NMN accordingly
  • Elysium funded COPD trial (Norheim 2024) and separates from ChromaDex ecosystem
  • Three null NMN meta-analyses (2024-2025) arrive with author statements that the field "exaggerates benefits" — rare explicit call-out
  • Hazen lab has no commercial supplement interest, strengthening 4PY finding's credibility
  • ONTRAC positive + ONTRANS negative together show nicotinamide benefit is population-specific — a common bias is to cite ONTRAC without ONTRANS

Manipulation Flags (Mode 2)

  • Industry marketing: "Clinically proven to raise NAD+" language on virtually all NR/NMN labels. Label claims trade on surrogate endpoint while implying clinical outcomes. "No-flush niacin" (inositol hexanicotinate) is a persistent market category despite Meyers 2003 showing near-zero biological activity.
  • Influencer economics: Sinclair (MetroBiotech, Tally, Leap Years + media saturation across Rogan/Attia/Huberman); Brenner (ChromaDex CSO); Rhonda Patrick (Tru Niagen affiliate); Dave Asprey (NR → NMN affiliate shift); Ben Greenfield, Siim Land (affiliate economies); Charles Brenner's "longevity skeptic" media positioning is itself commercially aligned.
  • Counter-narrative manipulation: "Statins suppressed niacin to protect their market" is a conspiracy-adjacent framing used in orthomolecular spaces. HPS2-THRIVE is a real 25,673-patient trial with excess AEs; Cochrane 2017 is an independent meta. The 2024 Hazen mechanism paper further weakens the conspiracy frame.
  • Cui bono summary: Positive hype benefits ChromaDex (NR), MetroBiotech/Shinkowa/Mitsubishi (NMN), Niagen Bioscience, Sinclair's companies, affiliate podcasters, Japanese premium NMN retail. Negative hype benefits statin manufacturers marginally (niacin was never meaningful competition post-2014). The asymmetry is heavily tilted toward pro-supplement manipulation, not pharma-fearmongering.
  • Supply chain economics: NMN raw material cost ~$2-3/month for 500 mg/day; retail $40-80/month. NR similar markup. Japanese premium NMN $600-1300/bottle reflects consumer price insensitivity, not manufacturing cost.
  • Red team highlight (10 angles): The most concerning angle is historical precedent — vitamin E raised antioxidant biomarkers, didn't translate to clinical benefit, and chronic high-dose was eventually associated with mortality signals. NR/NMN reliably raise the surrogate (NAD+); clinical translation at 10+ years of RCTs has produced few durable wins and the Hazen 2024 paper reveals niacin's terminal metabolite is atherogenic. A scenario where 2035 NR/NMN data looks like 2015 vitamin E data is plausible.

Decision Support (Mode 3 — Clarity Compass)

  • Health utility score: 5/10 — strong for deficiency states and NMSC secondary prevention (immunocompetent); weak-to-null for the longevity/metabolic claims that drive market hype; definitively negative for the historical cardiovascular indication. Evaluated independently of any current stack or goal set.
  • Opportunity cost: Nicotinamide is negligible ($3-8/mo); NR/NMN meaningful ($35-80/mo, tolerance for 2/5 clinical evidence). Niacin for lipids is now an active harm to avoid.
  • Verdict: CONDITIONAL
    • Nicotinamide 500 mg BID — CONDITIONAL for immunocompetent adults with ≥2 prior NMSC (strong evidence); baseline nicotinamide 250-500 mg/day as a low-cost NAD+-support / anxiolytic / sleep option is a reasonable WATCH-tier choice for motivated users
    • NR 300-1000 mg/day — WATCH LIST; biochemistry real, disease-modifying signals sparse; reasonable for highly motivated users ≥50 who accept 2/5 clinical evidence and premium cost; AVOID during training cycles for athletes
    • NMN 250-500 mg/day — WATCH LIST; regulatory uncertainty resolved (2025), but three null meta-analyses and the Christen 2026 mechanism paper argue against preferential selection over NR
    • Niacin for CVD — SKIP definitively (Cochrane 2017 + Hazen 2024)
    • Niacin for severe hypertriglyceridemia — CONDITIONAL only after statin + fibrate failure, under specialist care
    • Inositol hexanicotinate "no-flush niacin" — SKIP (does not release meaningful niacin)
  • Conditions (if conditional): NMSC history (≥2 prior), documented pellagra/deficiency, INH therapy in malnourished patient, severe hypertriglyceridemia unresponsive to standard care, or emerging evidence-based indication (glaucoma pending NAMinG 2027).

Bottom Line

Vitamin B3 is four compounds with four evidence profiles. The strongest real-world utility is deficiency repletion (pellagra, alcoholism, INH) and nicotinamide for NMSC secondary prevention in immunocompetent adults. The longevity industry's flagship promise — NR and NMN reversing aging — remains at the "raises a surrogate" stage after a decade of trials, with three 2024-2025 meta-analyses explicitly null on the metabolic and muscle endpoints that most users care about. The 2024 Hazen/Ferrell paper is the most important B3 development of the decade: niacin's 4PY metabolite is mechanistically atherogenic, consolidating the case that the historical CV indication was not just null but actively harmful. The 2026 Christen paper consolidates the case that NR and NMN are biochemically interchangeable via gut microbiota, collapsing most product-differentiation marketing. Use nicotinamide for pellagra, NMSC prevention, and general NAD+ support. Avoid niacin for lipids. Treat NR/NMN as an expensive optimism trade with real biochemistry and thin clinical outcomes.

Practical Notes

Brands & Product Selection

Nicotinamide: Now Foods 500 mg (cheap, reliable); Thorne (premium, COA-transparent); Life Extension; Source Naturals. Avoid anything labeled "niacin" if you want nicotinamide — conflation is pervasive.

Niacin: Nature's Bounty / Now IR 500 mg (generic, OK); Life Extension (premium IR). AVOID: any SR (slow-release) niacin, including Slo-Niacin. Niaspan Rx ER is available but guideline-abandoned and expensive. Inositol hexanicotinate from Solgar / Cardiovascular Research / Now: marketing-only — does not meaningfully release niacin per Meyers 2003.

NR: Tru Niagen (Niagen Bioscience, market leader, assay-verified); Thorne Niacel 400; Life Extension NAD+ Cell Regenerator; Elysium Basis (NR + pterostilbene, premium); ProHealth Longevity NR. Off-brand NR (Jarrow, Swanson) has variable assay — ChromaDex 2024 industry survey found 87% of non-branded NR products missed label (conflicted source, treat directionally).

NMN: Renue By Science (liposomal/sublingual, transparent COAs); ProHealth Longevity Uthever (clinically-studied raw material); DoNotAge (EU-favored, good $/mg); Jinfiniti Vitality Boost; Alive By Science; NOVOS Core (combined longevity formula, Sinclair-adjacent messaging). Japan-exclusive premium: Shinkowa NMN PURE series (99.8% purity, cult-status but $600-1300/bottle). Avoid no-name Amazon NMN below $0.10/mg — quality assay is unreliable.

Topical niacinamide: The Ordinary Niacinamide 10% + Zinc 1% ($7, value pick); Paula's Choice 10% Booster; Anua 10 + TXA 4 (K-beauty, hyperpigmentation); CeraVe / La Roche-Posay drugstore formulations (paired with barrier agents).

Storage & Handling

  • Nicotinamide, niacin: stable at room temp, 2-year shelf life; keep dry
  • NR: moisture-sensitive; refrigerate after opening to preserve stability
  • NMN: moisture and light-sensitive; refrigerate after opening; some retailers ship with ice packs
  • Topical niacinamide: degrades to niacin (flushing-capable) in aqueous formulations if pH drifts — buy brands with pH control and opaque packaging

Palatability & Compliance

  • Niacinamide: tasteless, easily taken with any meal
  • NR: capsules preferred; powder is bitter
  • NMN: sublingual is premium community choice; powder is neutral to slightly sweet
  • Niacin IR: flushing compliance is the #1 reason for discontinuation — expect 1-2 weeks of flushing before tachyphylaxis develops

Exercise & Circadian Timing

  • All NAD+ precursors: morning dosing is community rule; evening dosing causes insomnia in a common minority
  • NR specifically: the Dollerup 2020 Sci Adv rat paper suggests NR may blunt training-induced mitochondrial adaptations in high-volume training — conservative recommendation is to skip NR during peak training cycles for athletes
  • Niacin: take with the largest meal of the day to slow absorption and reduce flushing peak
  • Aspirin 325 mg 30 minutes before niacin dose reduces flushing intensity via COX blockade

Reference Ranges (Expected Biomarker Changes)

BiomarkerBaseline RangeExpected ChangeTimeline
Whole-blood NAD+30-70 µM (age-dependent)+40-150% with NR 300-1000 mg2-4 wk
Whole-blood NAD+ (NMN)Same+11-38% with NMN 250-1250 mg2-4 wk
Urinary N-methylnicotinamide>0.8 mg/g creatinine (sufficient)Rises with supplementationDays
HDL-C (niacin)+20-35%4-12 wk
Triglycerides (niacin)-20-40%4-12 wk
Lp(a) (niacin)-20-30%4-12 wk
HbA1c (niacin)+0.3-0.5% (adverse)6-12 wk
2PY / 4PYVariableRise with niacin (atherogenic per Hazen 2024)Days

Cost (USD/month)

  • Nicotinamide 500 mg BID: $3-8
  • Niacin IR 500 mg: $5-12
  • NR 300 mg: $35 (Tru Niagen subscription) to $60 (retail)
  • NR 1000 mg: $60-90
  • NMN 500 mg: $40-80
  • NMN 1000 mg: $80-150
  • Topical niacinamide 10%: $7-40
  • Japanese premium NMN: $300-1300 (status/gift purchasing, not cost-effective)

What We Don't Know

  • Whether any NAD+ precursor extends healthspan or lifespan in humans (Gallagher 2026 PRISMA)
  • Whether Ferrell/Hazen 4PY atherogenesis replicates in independent cohorts and whether it applies to dietary (RDA) niacin vs pharmacologic doses only
  • Whether NMSC prevention extends to primary prevention in unaffected adults
  • Whether NAMinG Ph3 glaucoma trial (2027 readout) validates the Hui/De Moraes Ph2 signal
  • Whether MIB-626 Ph2 (Sinclair/Metro Biotech, results pending) changes NMN's clinical profile
  • Whether long-term (>5 yr) high-dose NR/NMN has late-emerging oncologic or metabolic signals
  • Whether gut microbiota composition (Christen 2026) predicts individual NR/NMN response enough to be clinically actionable
  • Whether Slc12a8 direct NMN transport exists in humans (mouse-dominant evidence, human dispute)
  • Whether the rat training-adaptation-blunting signal (Dollerup 2020) applies to human athletes
  • Whether pellagra case definitions need updating for subclinical presentations in modern high-income populations
  • Whether trigonelline (coffee, fenugreek) supplementation supports NAD+ status as suggested by Membrez 2024

References

Meta-analyses & Systematic Reviews

  • Schandelmaier 2017 Cochrane PMID 28616955 — 23 RCTs/N=39,195 niacin no CV benefit (definitive)
  • Prokopidis 2025 J Cachexia Sarcopenia Muscle PMID 40275690 — NR+NMN null for sarcopenia ≥60
  • Chen 2024 Curr Diab Rep PMID 39531138 — NMN null for glucose/lipid (8 RCTs)
  • Zhang 2025 Crit Rev Food Sci Nutr PMID 39116016 — NMN null; authors: "exaggeration of benefits may exist"
  • Oliveira-Cruz 2024 Horm Metab Res PMID 39111741 — NAD+ precursors metabolic syndrome null
  • Zhang 2026 Nutrients PMID 41901064 — NMN DBP -2.15 mmHg (modest, ≥60 subgroup)
  • Gallagher 2026 Ageing Res Rev PMID 41655607 — PRISMA 113 studies: NAD+ anti-aging inconclusive
  • Mainville 2022 J Cutan Med Surg PMID 35134311 — nicotinamide NMSC meta
  • Rad 2024 Eur J Nutr PMID 38761279 — niacin inflammation modest

Landmark RCTs

  • Chen 2015 NEJM PMID 26488693 — ONTRAC: nicotinamide 500 mg BID -23% NMSC (positive)
  • Allen 2023 NEJM PMID 36856616 — ONTRANS: nicotinamide failed in kidney transplant (negative)
  • HPS2-THRIVE 2014 NEJM PMID 25014686 — N=25,673, niacin no CV benefit, excess AEs
  • AIM-HIGH 2011 NEJM PMID 22085343 — N=3,414, niacin no benefit, stopped for futility
  • Yoshino 2021 Science PMID 33888596 — NMN 250 mg improved muscle insulin signaling, prediabetic PM women
  • Martens 2018 Nat Commun PMID 29599478 — NR 1000 mg raised NAD+ 60% healthy adults
  • Dellinger 2017 PMID 29184669 — NR dose-response human
  • Orr 2023 Geroscience PMID 36859743 — NR null for MCI cognition
  • Dollerup 2018 AJCN PMID 29992272 — NR null for insulin sensitivity in obese men
  • Norheim 2024 Nat Aging PMID 39548320 — NR positive for COPD airway IL-8
  • McDermott 2024 Nat Commun PMID 38871717 — NICE: NR modestly positive for PAD 6-min walk
  • Wu 2025 Alzheimers Dement PMID 39817194 — NR lowered pTau-217 in MCI (biomarker signal)
  • Wu 2025 EClinicalMedicine PMID 41357333 — NR null for long-COVID cognition/fatigue
  • Shoji 2025 Aging Cell PMID 40459998 — NR positive for Werner syndrome
  • Lin 2025 Geroscience PMID 40770531 — NR+Ex null for HTN
  • Morifuji 2024 Geroscience PMID 38789831 — NMN positive for older-adult walking/sleep (Japan)
  • Hwang 2025 Arch Dermatol Res PMID 40498148 — nicotinamide SOTR cohort NMSC (extends ONTRAC to immunosuppressed)
  • Hui 2020 PMID 32721104 & De Moraes 2022 JAMA Ophthalmol PMID 34792559 — nicotinamide Ph2 glaucoma positive
  • Pencina 2023 JCEM PMID 36740954 — MIB-626 (NMN) raised NAD+ but no functional change

Mechanism

  • Ferrell/Hazen 2024 Nat Med PMID 38374343 — 4PY niacin metabolite causally drives endothelial VCAM-1 and predicts MACE
  • Christen 2026 Nat Metab PMID 41540253 — NR and NMN both require gut-microbial conversion to nicotinic acid for NAD+ elevation; collapses product differentiation
  • Singh 2014 Immunity PMID 24412617 — GPR109A activation suppresses colonic inflammation (IBD mechanism)
  • Cantó 2015 Cell Metab PMID 26118927 — NAD+ metabolism energy homeostasis review
  • Verdin 2015 Science PMID 26785480 — NAD+ in aging
  • Bieganowski & Brenner 2004 Cell PMID 15137942 — NR kinase discovery
  • Lautrup 2019 Cell Metab PMID 31577934 — NAD+ in brain aging
  • Migaud 2024 Nat Rev Mol Cell Biol (W4400772772) — gold-standard mechanism review
  • Javaid 2024 Arch Biochem Biophys PMID 39322100 — niacin flushing mechanism (GPR109A + TRPV1)
  • Membrez 2024 Nat Metab (W4392956639) — trigonelline as novel NAD+ precursor

Safety & Regulatory

  • McKenney 1994 JAMA PMID 8309029 — SR vs IR niacin: SR higher hepatotoxicity
  • Nawaz 2024 PMID 38193433 — fatal cholestatic DILI from self-dosed ER niacin (single case)
  • Camillo 2025 Medicina PMID 40005371 — skin health mechanism; 3 g/day nicotinamide safe long-term
  • Tan/Williams 2026 Am J Clin Dermatol PMID 41505062 — "Jury Was Out and Still is" NMSC reappraisal
  • Conze 2016 Hum Exp Toxicol PMID 26823174 — NR safety/GRAS

Guidelines

  • AACE 2025 PMID 39919851 — dyslipidemia, niacin de-emphasized
  • ACC/AHA 2018 PMID 30586775 — niacin severe hypertriglyceridemia adjunct only
  • ESPEN 2022 PMID 35365361 — micronutrient guideline
  • Stratigos 2020 PMID 32113941 — European SCC guideline
  • Hołubiec 2021 PMID 34882669 — pellagra clinical review
  • Nabity 2022 Lancet Glob Health PMID 35427527 — INH pellagra Malawi context
  • Hegyi 2004 Int J Dermatol PMID 14693013 — pellagra clinical review

Key External References

  • NIH Office of Dietary Supplements — Niacin Fact Sheet for Health Professionals
  • BioMCP FAERS aggregate data (2026-04-17 snapshot)
  • ClinicalTrials.gov via BioMCP biomcp search trial -c [form]